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Issue 79, 2012
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Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

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Abstract

A decanuclear Cd complex has been found as a carbonate-containing capsule. The structure strongly resembles a ten-blade waterwheel with a central carbonate ligand surrounded by two superimposed Cd5O5 crowns with a pentagonal antiprism-like disposition. The capsule is doubly capped by two pentadentate perchlorate anions.

Graphical abstract: Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

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Publication details

The article was received on 18 Jul 2012, accepted on 17 Aug 2012 and first published on 20 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35171D
Citation: Chem. Commun., 2012,48, 9915-9917
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    Encapsulation of atmospheric CO2 by a self-assembled decanuclear cadmium complex via unfamiliar perchlorato and carbonato bridges

    A. M. García-Deibe, C. Portela-García, M. Fondo, A. J. Mota and J. Sanmartín-Matalobos, Chem. Commun., 2012, 48, 9915
    DOI: 10.1039/C2CC35171D

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