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Issue 85, 2012
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A hydrogen bond scaffold supported synthetic heme FeIII–O2 adduct

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Abstract

A hydrogen bonded heme-FeIII–O2 adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O–O vibrations of this complex are quite different from those reported for other heme-FeIII–O2 adducts.

Graphical abstract: A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct

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Publication details

The article was received on 18 Jul 2012, accepted on 30 Aug 2012 and first published on 31 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35162E
Citation: Chem. Commun., 2012,48, 10535-10537
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    A hydrogen bond scaffold supported synthetic heme FeIII–O2 adduct

    K. Mittra, S. Chatterjee, S. Samanta, K. Sengupta, H. Bhattacharjee and A. Dey, Chem. Commun., 2012, 48, 10535
    DOI: 10.1039/C2CC35162E

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