A hydrogen bonded heme-FeIII–O2− adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O–O vibrations of this complex are quite different from those reported for other heme-FeIII–O2− adducts.
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A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct
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Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, India
E-mail: icad@iacs.res.in ;
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Tel: +91-33-2473 4971
E-mail: icad@iacs.res.in ;
Fax: +91-33-2473 2805 ;
Tel: +91-33-2473 4971
Chem. Commun., 2012,48, 10535-10537
DOI: 10.1039/C2CC35162E
Received 18 Jul 2012, Accepted 30 Aug 2012
First published online 31 Aug 2012
Chemical Communications
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