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Issue 83, 2012
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Heterogeneous asymmetric Henry–Michael one-pot reaction synergically catalyzed by grafted chiral bases and inherent achiral hydroxyls on mesoporous silica surface

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Abstract

Highly efficient and enantioselective asymmetric Henry–Michael one-pot reaction has been achieved on bifunctional heterogeneous catalysts with inherent achiral hydroxyls as acidic sites and immobilized chiral amines as basic sites. Final products were afforded in yields of up to 85% and ee of 99%.

Graphical abstract: Heterogeneous asymmetric Henry–Michael one-pot reaction synergically catalyzed by grafted chiral bases and inherent achiral hydroxyls on mesoporous silica surface

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Publication details

The article was received on 17 Jul 2012, accepted on 30 Aug 2012 and first published on 31 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35110B
Citation: Chem. Commun., 2012,48, 10349-10351
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    Heterogeneous asymmetric Henry–Michael one-pot reaction synergically catalyzed by grafted chiral bases and inherent achiral hydroxyls on mesoporous silica surface

    S. Yang and J. He, Chem. Commun., 2012, 48, 10349
    DOI: 10.1039/C2CC35110B

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