Carbon nanoparticles were obtained at room temperature by irradiating an organogel made from a 1,8-diaryloctatetrayne derivative in chloroform. During the topochemical polymerization, the morphology of the gel changes from fibers to soluble, yellow fluorescent nanoparticles in high yield. Analyses suggest that the resulting nanoparticles are made of amorphous graphitic carbon.
Chemical Communications
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