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Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
; Fax: +8610 6279 6761
; Tel: +8610 6279 7527
Chem. Commun., 2012,48, 9418-9420
16 Jul 2012,
01 Aug 2012
First published online
03 Aug 2012
The stable and structurally well-defined Ar–Cu(III) intermediates, that are prepared almost quantitatively from the reaction of azacalixarenepyridines with Cu(ClO4)2·6H2O under aerobic conditions, reacted smoothly with a number of alkyllithium reagents under mild conditions to form Caryl–Calkyl bonds.
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