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Issue 75, 2012
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Caryl–Calkyl bond formation from Cu(ClO4)2-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar–Cu(III) intermediates

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Abstract

The stable and structurally well-defined Ar–Cu(III) intermediates, that are prepared almost quantitatively from the reaction of azacalix[1]arene[3]pyridines with Cu(ClO4)2·6H2O under aerobic conditions, reacted smoothly with a number of alkyllithium reagents under mild conditions to form Caryl–Calkyl bonds.

Graphical abstract: Caryl–Calkyl bond formation from Cu(ClO4)2-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar–Cu(iii) intermediates

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Publication details

The article was received on 16 Jul 2012, accepted on 01 Aug 2012 and first published on 03 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35067J
Citation: Chem. Commun., 2012,48, 9418-9420
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    Caryl–Calkyl bond formation from Cu(ClO4)2-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar–Cu(III) intermediates

    Z. Wang, L. Zhao and M. Wang, Chem. Commun., 2012, 48, 9418
    DOI: 10.1039/C2CC35067J

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