In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed–armed iterative glycosylation

Yu Hsien Lin; Bhaswati Ghosh; Kwok-Kong Tony Mong

doi:10.1039/C2CC35032G

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Chemical Communications

Issue 88, 2012

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In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed–armed iterative glycosylation

Yu Hsien Lin,^a Bhaswati Ghosh^a and Kwok-Kong Tony Mong*^a

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1001, Ta Hsueh Road, Hsinchu, Taiwan
E-mail: tmong@mail.nctu.edu.tw ;
Fax: +886-3-5131204 ;
Tel: +886-3-5712121

Chem. Commun., 2012,48, 10910-10912

DOI: 10.1039/C2CC35032G
Received 13 Jul 2012, Accepted 17 Sep 2012
First published online 18 Sep 2012

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Abstract
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β-Glycosyl imidinium triflate is generated from participating thioglycoside donors for disarmed–armed iterative glycosylations and one-pot oligosaccharide synthesis.