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Issue 85, 2012
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Ping-pong polymerization by allylation and hydroformylation for alternating vinyl alcohol–vinyl monomer copolymers

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Abstract

Inspired by the enzymatic ping-pong mechanism, we designed a novel “ping-pong polymerization”, which employs allylation and hydroformylation in an iterative and alternating manner. Thus, alternating and regioregular vinyl alcohol–vinyl monomer copolymers possessing multiple hydroxy groups in a periodical manner were successfully synthesized.

Graphical abstract: Ping-pong polymerization by allylation and hydroformylation for alternating vinyl alcohol–vinyl monomer copolymers

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Publication details

The article was received on 12 Jul 2012, accepted on 23 Aug 2012 and first published on 24 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC34980A
Citation: Chem. Commun., 2012,48, 10481-10483
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    Ping-pong polymerization by allylation and hydroformylation for alternating vinyl alcohol–vinyl monomer copolymers

    S. Ito, M. Noguchi and K. Nozaki, Chem. Commun., 2012, 48, 10481
    DOI: 10.1039/C2CC34980A

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