Copper-catalyzed conversion of aryl and heteroaryl bromides into the corresponding chlorides

Xiujuan Feng; Yiping Qu; Yanlei Han; Xiaoqiang Yu; Ming Bao; Yoshinori Yamamoto

doi:10.1039/C2CC34944B

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Chemical Communications

Issue 76, 2012

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Copper-catalyzed conversion of aryl and heteroaryl bromides into the corresponding chlorides

Xiujuan Feng,*^a Yiping Qu,^a Yanlei Han,^a Xiaoqiang Yu,^a Ming Bao*^a and Yoshinori Yamamoto^a^b

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State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China
E-mail: mingbao@dlut.edu.cn ;
Fax: +86-0411-84986180 ;
Tel: +86-0411-84986180

WPI-AIMR (WPI-Advanced Institute for Materials Research), Tohoku University, Sendai 980-8577, Japan

Chem. Commun., 2012,48, 9468-9470

DOI: 10.1039/C2CC34944B
Received 11 Jul 2012, Accepted 02 Aug 2012
First published online 02 Aug 2012

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An efficient method for the synthesis of aryl and heteroaryl chlorides is described. The reactions of aryl and heteroaryl bromides with tetramethylammonium chloride proceeded smoothly in the presence of a copper catalyst under mild reaction conditions to produce the corresponding chlorides in satisfactory to excellent yields.

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Xiujuan Feng
Yiping Qu
Yanlei Han
Xiaoqiang Yu
Ming Bao
Yoshinori Yamamoto

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