Silica–(ZIF-8) core–shell spheres with tuneable ordered meso–microporosity have been synthesized, showing that the hydrophobic micropore ZIF-8 shell controls the access of guest molecules into the hydrophilic silica mesoporous structure.
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Ordered mesoporous silica–(ZIF-8) core–shell spheres
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Department of Chemical and Environmental Engineering and Instituto de Nanociencia de Aragón (INA), Universidad de Zaragoza, 50018 Zaragoza, Spain
E-mail: ctellez@unizar.es ;
Fax: +34 976 761879 ;
Tel: +34 976 762897
E-mail: ctellez@unizar.es ;
Fax: +34 976 761879 ;
Tel: +34 976 762897
Chem. Commun., 2012,48, 9388-9390
DOI: 10.1039/C2CC34893D
Received 09 Jul 2012, Accepted 31 Jul 2012
First published online 02 Aug 2012
Chemical Communications
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