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Copper-catalyzed coupling reaction of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as an effective additive

Ruwei Shen,a   Takanori Iwasaki,a   Jun Teraob and   Nobuaki Kambe*a  
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a
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: kambe@chem.eng.osaka-u.ac.jp;
Fax: +81-6-6879-7390 ;
Tel: +81-6-6879-7390
b
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
Chem. Commun., 2012,48, 9313-9315

DOI: 10.1039/C2CC34847K
Received 07 Jul 2012, Accepted 25 Jul 2012
First published online 13 Aug 2012
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