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Issue 70, 2012
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Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

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Abstract

Water oxidation catalysts: evolution of [Co4(H2O)2(α-PW9O34)2]10− to catalytically active species is assessed by laser flash photolysis in sacrificial photocatalytic cycles with Ru(bpy)32+ as a photosensitizer.

Graphical abstract: Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

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Publication details

The article was received on 05 Jul 2012, accepted on 16 Jul 2012 and first published on 26 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34804G
Citation: Chem. Commun., 2012,48, 8808-8810
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    Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

    M. Natali, S. Berardi, A. Sartorel, M. Bonchio, S. Campagna and F. Scandola, Chem. Commun., 2012, 48, 8808
    DOI: 10.1039/C2CC34804G

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