Issue 70, 2012

Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

Abstract

Water oxidation catalysts: evolution of [Co4(H2O)2(α-PW9O34)2]10− to catalytically active species is assessed by laser flash photolysis in sacrificial photocatalytic cycles with Ru(bpy)32+ as a photosensitizer.

Graphical abstract: Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

Supplementary files

Article information

Article type
Communication
Submitted
05 Jul 2012
Accepted
16 Jul 2012
First published
26 Jul 2012

Chem. Commun., 2012,48, 8808-8810

Is [Co4(H2O)2(α-PW9O34)2]10− a genuine molecular catalyst in photochemical water oxidation? Answers from time-resolved hole scavenging experiments

M. Natali, S. Berardi, A. Sartorel, M. Bonchio, S. Campagna and F. Scandola, Chem. Commun., 2012, 48, 8808 DOI: 10.1039/C2CC34804G

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