Issue 77, 2012
From the journal:

Chemical Communications

Fluorocyclohexanes: synthesis and structure of all-syn-1,2,4,5-tetrafluorocyclohexane†

Alastair J. Durie,a   Alexandra M. Z. Slawin,a   Tomas Lebl,a   Peer Kirschb  and  David O'Hagan*a  

* Corresponding authors

a University of St Andrews, School of Chemistry and Centre for Biomolecular Sciences, North Haugh, St Andrews, Fife, UK
E-mail: do1@st-andrews.ac.uk
Fax: +44 (0)1334 463800
Tel: +44 (0)1334 467171

b Merck KGaA, Frankfurter Str. 250, D 64293 Darmstadt, Germany

Abstract

The all-syn isomer of 1,2,4,5-tetrafluorocyclohexane is prepared and characterised by NMR and X-ray crystallography. It emerges to be a particularly polar cyclohexane analogue with differentially polarised faces.

Graphical abstract: Fluorocyclohexanes: synthesis and structure of all-syn-1,2,4,5-tetrafluorocyclohexane

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Article information

DOI
https://doi.org/10.1039/C2CC34679F
Article type
Communication
Submitted
29 Jun 2012
Accepted
03 Aug 2012
First published
06 Aug 2012

Chem. Commun., 2012,48, 9643-9645

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Fluorocyclohexanes: synthesis and structure of all-syn-1,2,4,5-tetrafluorocyclohexane

A. J. Durie, A. M. Z. Slawin, T. Lebl, P. Kirsch and D. O'Hagan, Chem. Commun., 2012, 48, 9643 DOI: 10.1039/C2CC34679F

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