Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2

Yu He; Christian R. Goldsmith

doi:10.1039/C2CC34634F

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Chemical Communications

Issue 85, 2012

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Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O₂

Yu He^a and Christian R. Goldsmith*^a

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Auburn University, Department of Chemistry and Biochemistry, Auburn, USA
E-mail: crgoldsmith@auburn.edu

Chem. Commun., 2012,48, 10532-10534

DOI: 10.1039/C2CC34634F
Received 28 Jun 2012, Accepted 06 Sep 2012
First published online 19 Sep 2012

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A non-heme iron complex catalyses the oxidation of allylic, benzylic, and aliphatic C–H bonds by O₂. During this reactivity, a ferric hydroperoxide species is observed. The kinetic analysis of this complex's formation may suggest a ferric superoxo species as the initial metal-based oxidant.

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Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2

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Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O₂