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Issue 74, 2012
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Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

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Abstract

Kinetic and DFT studies revealed that protonation of Ti-containing polyoxometalates (Ti-POM) lowers significantly the energy barrier for the heterolytic oxygen transfer from the Ti hydroperoxo intermediate to the alkene, increasing the activity and selectivity of alkene oxidation.

Graphical abstract: Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

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Publication details

The article was received on 26 Jun 2012, accepted on 25 Jul 2012 and first published on 10 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC34577C
Citation: Chem. Commun., 2012,48, 9266-9268
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    Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

    P. Jiménez-Lozano, I. D. Ivanchikova, O. A. Kholdeeva, J. M. Poblet and J. J. Carbó, Chem. Commun., 2012, 48, 9266
    DOI: 10.1039/C2CC34577C

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