Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

Pablo Jiménez-Lozano; Irina D. Ivanchikova; Oxana A. Kholdeeva; Josep M. Poblet; Jorge J. Carbó

doi:10.1039/C2CC34577C

This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.

skip RSC | ChemSpider | Feedback

Home > Journals > Chemical Communications > Alkene oxidation by Ti-...

For Authors & Referees | For Librarians | For Members

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chemical Communications

Issue 74, 2012

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

Journal Home

Previous Article | Next Article

Communication

Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

Pablo Jiménez-Lozano,^a Irina D. Ivanchikova,^b Oxana A. Kholdeeva,*^b Josep M. Poblet*^a and Jorge J. Carbó*^a

Show Affiliations

Hide Affiliations

Corresponding authors

Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Campus Sescelades, C/Marcel.lí Domingo s/n, 43007 Tarragona, Spain
E-mail: josepmaria.poblet@urv.cat

Boreskov Institute of Catalysis, Lavrentiev av. 5, Novosibirsk 630090, Russia
E-mail: khold@catalysis.ru

Chem. Commun., 2012,48, 9266-9268

DOI: 10.1039/C2CC34577C
Received 26 Jun 2012, Accepted 25 Jul 2012
First published online 10 Aug 2012

Please wait while Download options loads

Download Citation

Request Permissions

Abstract
Cited by
Related Content

Kinetic and DFT studies revealed that protonation of Ti-containing polyoxometalates (Ti-POM) lowers significantly the energy barrier for the heterolytic oxygen transfer from the Ti hydroperoxo intermediate to the alkene, increasing the activity and selectivity of alkene oxidation.

Chemical Communications - Information Point

About this Journal

People and Contacts

Submit to this Journal

Editorial Board

Authors and Referees

Subscription Information

Follow Journal | |

Supplementary Info

Supplementary information
PDF (341K)

Search Articles By

Pablo Jiménez-Lozano
Irina D. Ivanchikova
Oxana A. Kholdeeva
Josep M. Poblet
Jorge J. Carbó

Terms & Conditions|Privacy and Cookies |Accessibility|ACAP Enabled

Chemical Communications

Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

Log in (Free Access)

Log in (Subscriber Access)

Supplementary Info

Search Articles By

Chemical Communications

Alkene oxidation by Ti-containing polyoxometalates. Unambiguous characterization of the role of the protonation state

This text is added as a work around for heading error in Accessibility testing

Log in (Free Access)

Log in (Subscriber Access)

Supplementary Info

Search Articles By