Reaction of a variety of 1,7-enynes with bis(pinacolato) diboron catalysed by Pd bis(trifluoroacetate) affords homoallylic and allylic boronates containing a six membered carbo- or heterocycle, by formation of C–C and C–B bonds
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Pd-catalyzed borylative cyclisation of 1,7-enynes
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Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain
E-mail: diego.cardenas@uam.es ;
Fax: +34 914973966 ;
Tel: +34 914974358
E-mail: diego.cardenas@uam.es ;
Fax: +34 914973966 ;
Tel: +34 914974358
Chem. Commun., 2012,48, 10517-10519
DOI: 10.1039/C2CC34468H
Received 21 Jun 2012, Accepted 16 Aug 2012
First published online 24 Aug 2012
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