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Issue 94, 2012
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New zeolite Al-COE-4: reaching highly shape-selective catalytic performance through interlayer expansion

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Abstract

A ferrierite-type layered aluminosilicate, Al-RUB-36, was prepared for the first time and its interlayer expansion resulted in new zeolite catalysts denoted Al-COE-3 and Al-COE-4. Decane hydroconversion tests demonstrated the highly active and shape-selective nature of the new Al-COE-4 catalyst with an unprecedented isomerization yield, highlighting the potential of this material as a hydroisomerization catalyst. This is the first report on achieving shape-selectivity via interlayer expansion.

Graphical abstract: New zeolite Al-COE-4: reaching highly shape-selective catalytic performance through interlayer expansion

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Publication details

The article was received on 20 Jun 2012, accepted on 10 Oct 2012 and first published on 11 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC34433E
Citation: Chem. Commun., 2012,48, 11549-11551
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    New zeolite Al-COE-4: reaching highly shape-selective catalytic performance through interlayer expansion

    B. Yilmaz, U. Müller, M. Feyen, H. Zhang, F. Xiao, T. De Baerdemaeker, B. Tijsebaert, P. Jacobs, D. De Vos, W. Zhang, X. Bao, H. Imai, T. Tatsumi and H. Gies, Chem. Commun., 2012, 48, 11549
    DOI: 10.1039/C2CC34433E

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