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Issue 73, 2012
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Chiral Brønsted acid catalyzed enantioselective allenylation of aldehydes

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Abstract

A versatile and highly enantioselective chiral Brønsted acid-catalyzed allenylation of aldehydes with propargyl borolane is reported. The reaction is shown to be practical and quite general with a broad substrate scope covering aryl, heteroaryl, α,β-unsaturated, and aliphatic aldehydes.

Graphical abstract: Chiral Brønsted acid catalyzed enantioselective allenylation of aldehydes

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Publication details

The article was received on 18 Jun 2012, accepted on 20 Jul 2012 and first published on 23 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34371A
Citation: Chem. Commun., 2012,48, 9189-9191
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    Chiral Brønsted acid catalyzed enantioselective allenylation of aldehydes

    L. R. Reddy, Chem. Commun., 2012, 48, 9189
    DOI: 10.1039/C2CC34371A

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