Electrochemically shape-controlled synthesis of trapezohedral platinum nanocrystals with high electrocatalytic activity

Yanyan Li; Yanxia Jiang; Minghui Chen; Honggang Liao; Rui Huang; Zhiyou Zhou; Na Tian; Shengpei Chen; Shigang Sun

doi:10.1039/C2CC34322C

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Chemical Communications

Issue 76, 2012

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

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Electrochemically shape-controlled synthesis of trapezohedral platinum nanocrystals with high electrocatalytic activity

Yanyan Li,^a Yanxia Jiang,*^a Minghui Chen,^a Honggang Liao,^a Rui Huang,^a Zhiyou Zhou,^a Na Tian,^a Shengpei Chen^a and Shigang Sun*^a

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Corresponding authors

State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
E-mail: sgsun@xmu.edu.cn

Chem. Commun., 2012,48, 9531-9533

DOI: 10.1039/C2CC34322C
Received 16 Jun 2012, Accepted 07 Aug 2012
First published online 08 Aug 2012

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Trapezohedral Pt nanocrystals enclosed by 24 high-index {522} facets have been successfully prepared for the first time in high yield by a direct square wave electrodeposition method. They exhibit a significantly enhanced catalytic activity for C-1 molecules (CO, CH₃OH, HCOOH).

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Yanyan Li
Yanxia Jiang
Minghui Chen
Honggang Liao
Rui Huang
Zhiyou Zhou
Na Tian
Shengpei Chen
Shigang Sun

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