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Issue 69, 2012
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Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

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Abstract

A unique N+–H⋯N hydrogen-bonded (H-bonded) dimer motif based on partially oxidized pyridyl-substituted TTF was constructed in the charge-transfer complex. The charge ordering in the TTF column by the charge disproportionation in the dimer regulates the arrangement of the H-bonded proton, evidencing the proton–electron coupled state.

Graphical abstract: Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

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Publication details

The article was received on 15 Jun 2012, accepted on 10 Jul 2012 and first published on 10 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC34296K
Citation: Chem. Commun., 2012,48, 8673-8675
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    Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative

    S. C. Lee, A. Ueda, H. Kamo, K. Takahashi, M. Uruichi, K. Yamamoto, K. Yakushi, A. Nakao, R. Kumai, K. Kobayashi, H. Nakao, Y. Murakami and H. Mori, Chem. Commun., 2012, 48, 8673
    DOI: 10.1039/C2CC34296K

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