Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes

Ge Wu; Jun Zhou; Min Zhang; Peng Hu; Weiping Su

doi:10.1039/C2CC34238C

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Chemical Communications

Issue 71, 2012

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Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes

Ge Wu,^a Jun Zhou,^a Min Zhang,^a Peng Hu^a and Weiping Su*^a

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State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: wpsu@fjirsm.ac.cn ;
Fax: +86 591 8377 1575 ;
Tel: +86 591 8377 1575

Chem. Commun., 2012,48, 8964-8966

DOI: 10.1039/C2CC34238C
Received 13 Jun 2012, Accepted 14 Jul 2012
First published online 16 Jul 2012

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Using CuBr₂ as an additive, the Pd-catalyzed intermolecular C–H–C–H cross-coupling between benzoxazoles and unactivated simple arenes has been developed. This protocol provides a straightforward approach for the biological activity of 2-arylbenzoxazole derivatives.

Abstract from Methods in Organic Synthesis 2013

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Ge Wu
Jun Zhou
Min Zhang
Peng Hu
Weiping Su

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