The effects of conformation on the noncovalent bonding interactions in a bistable donor–acceptor [3]catenane

Cheng Wang; Dennis Cao; Albert C. Fahrenbach; Sergio Grunder; Sanjeev K. Dey; Amy A. Sarjeant; J. Fraser Stoddart

doi:10.1039/C2CC34190E

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Chemical Communications

Issue 74, 2012

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The effects of conformation on the noncovalent bonding interactions in a bistable donor–acceptor [3]catenane

Cheng Wang,^a Dennis Cao,^a^b Albert C. Fahrenbach,^a^b Sergio Grunder,^a Sanjeev K. Dey,^a Amy A. Sarjeant^a and J. Fraser Stoddart*^a^b

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Center for the Chemistry of Integrated Systems, Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, USA
E-mail: stoddart@northwestern.edu ;
Fax: +1-847-491-1009 ;
Tel: +1-847-491-3793

NanoCentury KAIST Institute and Graduate School of EEWS (WCU), Korea Advanced Institute of Science and Technology (KAIST), 373-1, Guseong Dong, Yuseong Gu, Republic of Korea

Chem. Commun., 2012,48, 9245-9247

DOI: 10.1039/C2CC34190E
Received 11 Jun 2012, Accepted 13 Jul 2012
First published online 18 Jul 2012

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A switchable donor–acceptor bistable [3]catenane, composed of a crown ether containing a pair of alternating π-electron rich tetrathiafulvalene and 1,5-dioxynaphthalene units, encircled by two π-electron deficient cyclobis(paraquat-p-phenylene) rings, has been synthesised and the redox-activated switching it undergoes investigated.

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Cheng Wang
Dennis Cao
Albert C. Fahrenbach
Sergio Grunder
Sanjeev K. Dey
Amy A. Sarjeant
J. Fraser Stoddart

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Chemical Communications

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