A series of stable quadrupolar bis(p-aminophenyl)-carbo-benzenes, featuring both donor–donor–donor π-frustration and central macro-aromaticity, is described and compared to the acyclic dibutatrienylacetylene (DBA) reference series.
Urgent high quality communications from across the chemical sciences.
Impact Factor
6.169
100 Issues per Year
Indexed in MEDLINE
Communication
Highly π electron-rich macro-aromatics: bis(p-aminophenyl)-carbo-benzenes and their DBA acyclic references
Show Affiliations
Hide Affiliations
*
Corresponding authors
a
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, F-31077 Toulouse Cedex 4, France
E-mail: vmaraval@lcc-toulouse.fr ;
Fax: +33 (0)5 61 55 30 03 ;
Tel: +33 (0)5 61 33 31 13
E-mail: vmaraval@lcc-toulouse.fr ;
Fax: +33 (0)5 61 55 30 03 ;
Tel: +33 (0)5 61 33 31 13
b
Université de Toulouse, UPS, ICT-FR2599, F-31077 Toulouse, France
c
Kiev National Taras Shevchenko University, 60 Volodymlyrska St, 01033 Kiev, Ukraine
Chem. Commun., 2012,48, 8763-8765
DOI: 10.1039/C2CC34176J
Received 11 Jun 2012, Accepted 02 Jul 2012
First published online 03 Jul 2012
This article is part of themed collection:
Aromaticity
Chemical Communications
- Information Point
Supplementary Info
-
Supplementary information
PDF (773K) -
Crystal structure data
TXT (55K)