Enantioselective aza-Henry reactions of cyclic α-carbonyl ketimines under bifunctional catalysis

Alejandro Parra; Ricardo Alfaro; Leyre Marzo; Alberto Moreno-Carrasco; José Luis García Ruano; José Alemán

doi:10.1039/C2CC34053D

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Chemical Communications

Issue 78, 2012

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Enantioselective aza-Henry reactions of cyclic α-carbonyl ketimines under bifunctional catalysis

Alejandro Parra,^a Ricardo Alfaro,^a Leyre Marzo,^a Alberto Moreno-Carrasco,^a José Luis García Ruano^a and José Alemán*^a

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Corresponding authors

Departamento de Química Orgánica (Módulo 1), Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049-Madrid, Spain
E-mail: jose.aleman@uam.es

Chem. Commun., 2012,48, 9759-9761

DOI: 10.1039/C2CC34053D
Received 06 Jun 2012, Accepted 07 Aug 2012
First published online 08 Aug 2012

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The aza-Henry reaction of nitroalkanes with the C [double bond, length as m-dash] N group of 2-aryl-3H-indol-3-ones catalyzed by thiourea-chincona derivatives takes place with good yield and high ee's.