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Issue 71, 2012
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Organic acid induced olefination reaction of lactones

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Abstract

(Z)-Selective olefination of several lactones with ketene silyl acetals was achieved by the catalysis of carbon acids (C–H acids) having a bis(triflyl)methyl group as an acidic functionality; in particular, the triple carbon acid having three bis(triflyl)methyl groups in phloroglucinol shows an excellent catalytic performance.

Graphical abstract: Organic acid induced olefination reaction of lactones

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Publication details

The article was received on 18 May 2012, accepted on 18 Jul 2012 and first published on 18 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC33606E
Citation: Chem. Commun., 2012,48, 8967-8969
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    Organic acid induced olefination reaction of lactones

    H. Yanai and T. Taguchi, Chem. Commun., 2012, 48, 8967
    DOI: 10.1039/C2CC33606E

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