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Issue 74, 2012
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A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties

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Abstract

The compound (NBu4)5[GdIII{ReIVBr4(μ-ox)}4(H2O)]·H2O (1), with intramolecular antiferromagnetic coupling, is the first Re(IV) system incorporating a 4f ion.

Graphical abstract: A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties

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Publication details

The article was received on 09 May 2012, accepted on 24 Jul 2012 and first published on 26 Jul 2012


Article type: Communication
DOI: 10.1039/C2CC33350C
Citation: Chem. Commun., 2012,48, 9242-9244
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    A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties

    J. Martínez-Lillo, L. Cañadillas-Delgado, J. Cano, F. Lloret, M. Julve and J. Faus, Chem. Commun., 2012, 48, 9242
    DOI: 10.1039/C2CC33350C

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