The compound (NBu4)5[GdIII{ReIVBr4(μ-ox)}4(H2O)]·H2O (1), with intramolecular antiferromagnetic coupling, is the first Re(IV) system incorporating a 4f ion.
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A heteropentanuclear oxalato-bridged [ReIV4GdIII] complex: synthesis, crystal structure and magnetic properties
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a
Departament de Química Inorgánica/Instituto de Ciencia Molecular, Facultat de Química de la Universitat de València, Dr. Moliner 50, Burjassot, Spain
E-mail: juan.faus@uv.es
E-mail: juan.faus@uv.es
b
Instituto de Ciencia de Materiales de Aragón. CSIC-Universidad de Zaragoza C/ Pedro Cerbuna 12 E-50009 Zaragoza, Spain/Institut Laue Langevin, 6 Rue Jules Horowitz, B.P. 156, 38042 Grenoble, France
c
Fundació General de la Universitat de València (FGUV), Universitat de València, Valencia, Spain
Chem. Commun., 2012,48, 9242-9244
DOI: 10.1039/C2CC33350C
Received 09 May 2012, Accepted 24 Jul 2012
First published online 26 Jul 2012
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