Issue 51, 2012

Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds

Abstract

Oxidation of alkali metal derivatives of the dianions [E(tBuN)P(μ-NtBu)2P(NtBu)E]2− (E = S, Se) with I2 produces 15-membered macrocycles in which a planar P6E6 motif is stabilised by perpendicular P2N2 scaffolds.

Graphical abstract: Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds

Supplementary files

Article information

Article type
Communication
Submitted
19 Apr 2012
Accepted
02 May 2012
First published
03 May 2012

Chem. Commun., 2012,48, 6346-6348

Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds

A. Nordheider, T. Chivers, R. Thirumoorthi, I. Vargas-Baca and J. D. Woollins, Chem. Commun., 2012, 48, 6346 DOI: 10.1039/C2CC32809G

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