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Issue 54, 2012
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Formation of a surface covalent organic framework based on polyester condensation

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Abstract

The reaction between 1,3,5-tris(4-hydroxyphenyl)benzene and benzene-1,3,5-tricarbonyl trichloride leads to polyester condensation and formation of a novel COF on an Au(111) surface. The characterization performed in situ by means of variable temperature STM and XPS reveals the formation of an array of hexagonal cavities with ca. 2 nm size.

Graphical abstract: Formation of a surface covalent organic framework based on polyester condensation

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Publication details

The article was received on 29 Mar 2012, accepted on 14 Apr 2012 and first published on 16 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC32270F
Citation: Chem. Commun., 2012,48, 6779-6781
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    Formation of a surface covalent organic framework based on polyester condensation

    A. C. Marele, R. Mas-Ballesté, L. Terracciano, J. Rodríguez-Fernández, I. Berlanga, S. S. Alexandre, R. Otero, J. M. Gallego, F. Zamora and J. M. Gómez-Rodríguez, Chem. Commun., 2012, 48, 6779
    DOI: 10.1039/C2CC32270F

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