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Issue 41, 2012
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Isolation of reactive intermediates in deprotonation reactions with zinc alkyls

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Abstract

Using single crystal X-ray diffraction analysis and quantum chemical calculations, a model system for metalation reactions, the deprotonation of (tert-butylamino)(piperidinomethyl)dimethyl-silane (1) with Et2Zn, was established allowing for the isolation of a reactive intermediate, the adduct structure [1·Et2Zn] (2).

Graphical abstract: Isolation of reactive intermediates in deprotonation reactions with zinc alkyls

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Publication details

The article was received on 21 Mar 2012, accepted on 23 Mar 2012 and first published on 23 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC32057F
Citation: Chem. Commun., 2012,48, 5034-5036
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    Isolation of reactive intermediates in deprotonation reactions with zinc alkyls

    V. P. Colquhoun, C. Unkelbach and C. Strohmann, Chem. Commun., 2012, 48, 5034
    DOI: 10.1039/C2CC32057F

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