A dendritic nano-shell based on rigid phenylazomethine units can rectify electron transfer. By use of this function, the photo-induced charge separation was significantly enhanced due to the facilitated and stabilized radical ion pair.
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Electron-transfer through potential gradient based on a dendrimer architecture
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Chemical Resources Laboratory, Tokyo Institute of Technology, Nagatsuta-cho, Yokohama, Japan
E-mail: yamamoto@res.titech.ac.jp ;
Fax: +81-45-924-5260 ;
Tel: +81-45-924-5260
E-mail: yamamoto@res.titech.ac.jp ;
Fax: +81-45-924-5260 ;
Tel: +81-45-924-5260
Chem. Commun., 2012,48, 7235-7237
DOI: 10.1039/C2CC31954C
Received 17 Mar 2012, Accepted 13 Apr 2012
First published online 16 Apr 2012
Chemical Communications
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