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Issue 53, 2012
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A biocatalytic redox isomerisation

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Abstract

A bi-enzymatic cascade for the redox-isomerisation of allylic alcohol is presented. Coupling of an alcohol dehydrogenase to an enoate reductase has been successfully applied in one pot for the isomerisation of an allylic alcohol to the corresponding ketone. Critical parameters for yield and selectivity have been investigated.

Graphical abstract: A biocatalytic redox isomerisation

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Publication details

The article was received on 16 Mar 2012, accepted on 18 Apr 2012 and first published on 18 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31947K
Citation: Chem. Commun., 2012,48, 6630-6632
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    A biocatalytic redox isomerisation

    S. Gargiulo, D. J. Opperman, U. Hanefeld, I. W. C. E. Arends and F. Hollmann, Chem. Commun., 2012, 48, 6630
    DOI: 10.1039/C2CC31947K

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