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Issue 43, 2012
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An unprecedented ring-opening reaction of N-(aziridin-2-ylmethylene)hydrazines to facile synthesis of functionalized enamines catalysed by Lewis acid

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Abstract

An interesting Lewis acid-catalysed ring-opening reaction of N-(aziridin-2-ylmethylene)hydrazines has been described in this context. A variety of functionalized enamines could be obtained in good yields through a highly regioselective cleavage of a carbon–nitrogen single bond in the aziridines along with a 1,2-migration of the substituent.

Graphical abstract: An unprecedented ring-opening reaction of N-(aziridin-2-ylmethylene)hydrazines to facile synthesis of functionalized enamines catalysed by Lewis acid

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Publication details

The article was received on 15 Mar 2012, accepted on 03 Apr 2012 and first published on 04 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31911J
Citation: Chem. Commun., 2012,48, 5334-5336
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    An unprecedented ring-opening reaction of N-(aziridin-2-ylmethylene)hydrazines to facile synthesis of functionalized enamines catalysed by Lewis acid

    Z. Zhang, Y. Wei and M. Shi, Chem. Commun., 2012, 48, 5334
    DOI: 10.1039/C2CC31911J

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