Jump to main content
Jump to site search

Issue 48, 2012
Previous Article Next Article

Reactivity of terminal phosphinidene versus Li–Cl phosphinidenoid complexes in cycloaddition chemistry

Author affiliations

Abstract

Reaction of the thermally generated transient phosphinidene complex 2 and the Li–Cl phosphinidenoid complex 7 with N-methyl-thiophene-3-carbaldimine (3) was investigated. In the first case a mixture of azaphosphiridine complex 4 and bicyclic azaphospholene complex 5 was obtained; the reaction of complex 7 yielded selectively 5. DFT modelling of the reaction of 7 with 3 supports a nucleophilic formal [4+1] cycloaddition.

Graphical abstract: Reactivity of terminal phosphinidene versus Li–Cl phosphinidenoid complexes in cycloaddition chemistry

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Mar 2012, accepted on 24 Apr 2012 and first published on 25 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31851B
Citation: Chem. Commun., 2012,48, 5986-5988
  •   Request permissions

    Reactivity of terminal phosphinidene versus Li–Cl phosphinidenoid complexes in cycloaddition chemistry

    R. Streubel, J. M. V. Franco, G. Schnakenburg and A. E. Ferao, Chem. Commun., 2012, 48, 5986
    DOI: 10.1039/C2CC31851B

Search articles by author

Spotlight

Advertisements