Synthesis and application of a recyclable ionic liquid-supported imidazolidinone catalyst in enantioselective 1,3-dipolar cycloaddition

Zhi-Liang Shen; Kau Kiat Kelvin Goh; Colin Hong An Wong; Wan-Yi Loo; Yong-Sheng Yang; Jun Lu; Teck-Peng Loh

doi:10.1039/C2CC31830J

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Chemical Communications

Issue 47, 2012

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Synthesis and application of a recyclable ionic liquid-supported imidazolidinone catalyst in enantioselective 1,3-dipolar cycloaddition

Zhi-Liang Shen,^a Kau Kiat Kelvin Goh,^a Colin Hong An Wong,^a Wan-Yi Loo,^a Yong-Sheng Yang,^a Jun Lu^a and Teck-Peng Loh*^a

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Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
E-mail: teckpeng@ntu.edu.sg
Fax: +65-67911961

Chem. Commun., 2012,48, 5856-5858

DOI: 10.1039/C2CC31830J
Received 12 Mar 2012, Accepted 05 Apr 2012
First published online 05 Apr 2012

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The synthesis of recyclable ionic liquid-supported imidazolidinone catalyst I and its application in 1,3-dipolar cycloaddition of nitrone with α,β-unsaturated aldehyde with high performance were described. Most importantly, the catalyst I can be recovered and recycled for up to five runs without observing significant decrease in catalytic activity.

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Zhi-Liang Shen
Kau Kiat Kelvin Goh
Colin Hong An Wong
Wan-Yi Loo
Yong-Sheng Yang
Jun Lu
Teck-Peng Loh

Chemical Communications

Synthesis and application of a recyclable ionic liquid-supported imidazolidinone catalyst in enantioselective 1,3-dipolar cycloaddition

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