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Issue 46, 2012
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Induction of chirality: experimental evidence of atropisomerism in azapeptides

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Abstract

Methylation of the peptide bond in model azadipeptides leads to the E configuration and hence to atropisomerism due to a restricted rotation around the N–N axis.

Graphical abstract: Induction of chirality: experimental evidence of atropisomerism in azapeptides

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Publication details

The article was received on 16 Feb 2012, accepted on 17 Apr 2012, published on 18 Apr 2012 and first published online on 18 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31161E
Citation: Chem. Commun., 2012,48, 5772-5774
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    Induction of chirality: experimental evidence of atropisomerism in azapeptides

    P. A. Ottersbach, G. Schnakenburg and M. Gütschow, Chem. Commun., 2012, 48, 5772
    DOI: 10.1039/C2CC31161E

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