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Issue 40, 2012
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Enantioselective recognition by a highly ordered porphyrin-assembly on a chiral molecular gel

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Abstract

Enantioselective recognition of amino acids was achieved by using a highly ordered chiral assembly of achiral porphyrin on a chiral molecular gel. Exceptionally high enantioselectivity was observed for histidine derivatives by monitoring the CD patterns and fluorescence quenching, KSV (L): 26.3 × 103 M−1; KSV(D)-enantiomer: 7.03 × 103 M−1.

Graphical abstract: Enantioselective recognition by a highly ordered porphyrin-assembly on a chiral molecular gel

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Publication details

The article was received on 15 Feb 2012, accepted on 22 Mar 2012 and first published on 22 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC31127E
Citation: Chem. Commun., 2012,48, 4881-4883
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    Enantioselective recognition by a highly ordered porphyrin-assembly on a chiral molecular gel

    H. Jintoku, M. Takafuji, R. Oda and H. Ihara, Chem. Commun., 2012, 48, 4881
    DOI: 10.1039/C2CC31127E

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