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Issue 50, 2012
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Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

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Abstract

A new ZnPc–PDI dyad presenting for the first time a charge-separated state lower in energy than the triplet excited state of the ZnPc and PDI has been synthesized. The rational design implies the substitution of the ZnPc with phenoxy groups and the bay substitution of the PDI with sulfonyl substituents. The lifetime of the charge-separated state was 72 μs.

Graphical abstract: Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

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Publication details

The article was received on 14 Feb 2012, accepted on 02 May 2012 and first published on 04 May 2012


Article type: Communication
DOI: 10.1039/C2CC31087B
Citation: Chem. Commun., 2012,48, 6241-6243
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    Rational design of a phthalocyanine–perylenediimide dyad with a long-lived charge-separated state

    V. M. Blas-Ferrando, J. Ortiz, L. Bouissane, K. Ohkubo, S. Fukuzumi, F. Fernández-Lázaro and Á. Sastre-Santos, Chem. Commun., 2012, 48, 6241
    DOI: 10.1039/C2CC31087B

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