High-efficiency pyrene-based blue light emitting diodes: aggregation suppression using a calixarene 3D-scaffold

Khai Leok Chan; Jacelyn Pui Fong Lim; Xiaohui Yang; Ananth Dodabalapur; Ghassan E. Jabbour; Alan Sellinger

doi:10.1039/C2CC30995E

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Chemical Communications

Issue 42, 2012

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

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High-efficiency pyrene-based blue light emitting diodes: aggregation suppression using a calixarene 3D-scaffold

Khai Leok Chan,*^a Jacelyn Pui Fong Lim,^a Xiaohui Yang,^b Ananth Dodabalapur,^c Ghassan E. Jabbour*^b and Alan Sellinger*^d

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Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), 3 Research Link, Singapore 117602, Singapore
E-mail: chankl@imre.a-star.edu.sg

Solar and Alternative Energy Engineering Research Center, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia
E-mail: ghassan.jabbour@kaust.edu.sa

Microelectronics Research Center, University of Texas at Austin, Austin, USA

Center for Advanced Molecular Photovoltaics (CAMP), 476 Lomita Mall, Stanford University, Stanford, USA
E-mail: aselli@stanford.edu

Chem. Commun., 2012,48, 5106-5108

DOI: 10.1039/C2CC30995E
Received 10 Feb 2012, Accepted 29 Mar 2012
First published online 30 Mar 2012

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An efficient blue light emitting diode based on solution processable pyrene-1,3-alt-calix[4]arene is demonstrated, providing a record current efficiency of 10.5 cd A⁻¹ in a simple non-doped OLED configuration. Complete suppression of pyrene aggregation in the solid state is achieved by controlling chromophore dispersion using the 1,3-alt-calix[4]arene scaffold.

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Khai Leok Chan
Jacelyn Pui Fong Lim
Xiaohui Yang
Ananth Dodabalapur
Ghassan E. Jabbour
Alan Sellinger

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