Issue 32, 2012
From the journal:

Chemical Communications

Rational design of a NIR-emitting Pd(ii) sensor via oxidative cyclization to form a benzoxazole ring†

Weihua Chen,a   Brian D. Wrighta  and  Yi Pang*a  

* Corresponding authors

a Department of Chemistry & Maurice Morton Institute of Polymer Science, The University of Akron, Akron, USA
E-mail: yp5@uakron.edu
Tel: +1 330-972-8263

Abstract

By using the substituent effect to tune the palladium(II)-involved reactivity, a new probe is found to respond quantitatively to Pd(II). Unexpectedly, the probe gave an emission band in the desirable near-infrared (NIR) region (780 nm), thus providing the first NIR sensor for palladium detection.

Graphical abstract: Rational design of a NIR-emitting Pd(ii) sensor via oxidative cyclization to form a benzoxazole ring

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Article information

DOI
https://doi.org/10.1039/C2CC30240C
Article type
Communication
Submitted
11 Jan 2012
Accepted
22 Feb 2012
First published
23 Feb 2012

Chem. Commun., 2012,48, 3824-3826

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Rational design of a NIR-emitting Pd(II) sensor via oxidative cyclization to form a benzoxazole ring

W. Chen, B. D. Wright and Y. Pang, Chem. Commun., 2012, 48, 3824 DOI: 10.1039/C2CC30240C

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