Issue 12, 2012

Cascade reactions in crystals through cation–π-controlled reorientation on exposure to HCl gas

Abstract

Exposure of 4-azachalcones to HCl gas produced the corresponding HCl salts with a head-to-tail stacked alignment, irradiation of which produced the corresponding syn-HT dimers with high regio- and stereoselectivities, thus showing the effectiveness of the cascade process in crystals.

Graphical abstract: Cascade reactions in crystals through cation–π-controlled reorientation on exposure to HCl gas

Supplementary files

Article information

Article type
Communication
Submitted
12 Nov 2011
Accepted
13 Dec 2011
First published
14 Dec 2011

Chem. Commun., 2012,48, 1763-1765

Cascade reactions in crystals through cation–π-controlled reorientation on exposure to HCl gas

S. Yamada, Y. Tokugawa, Y. Nojiri and E. Takamori, Chem. Commun., 2012, 48, 1763 DOI: 10.1039/C2CC17019A

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