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Issue 6, 2012
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Touching the upper limit for ferromagnetic interactions in hetero-bridged dinuclear [Cu2II] complexes using a novel N5-dinucleating ligand bearing an endogenous monoatomic amido(R–NH)-bridging group

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Abstract

A novel N5-dinucleating ligand 4-amino-3,5-bis(bipyridine-2-yl)-1,2,4-triazole allows the preparation for the first time, and under mild conditions, of single and mixed amido(R–NH)-bridged copper(II) complexes, the latter exhibiting very strong ferromagnetic coupling.

Graphical abstract: Touching the upper limit for ferromagnetic interactions in hetero-bridged dinuclear [Cu2II] complexes using a novel N5-dinucleating ligand bearing an endogenous monoatomic amido(R–NH−)-bridging group

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Publication details

The article was received on 24 Oct 2011, accepted on 21 Nov 2011 and first published on 05 Dec 2011


Article type: Communication
DOI: 10.1039/C1CC16590A
Citation: Chem. Commun., 2012,48, 805-807
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    Touching the upper limit for ferromagnetic interactions in hetero-bridged dinuclear [Cu2II] complexes using a novel N5-dinucleating ligand bearing an endogenous monoatomic amido(R–NH)-bridging group

    E. Colacio, J. E. Perea-Buceta, A. J. Mota, E. K. Brechin, A. Prescimone, M. Hänninen, P. Seppälä and R. Sillanpää, Chem. Commun., 2012, 48, 805
    DOI: 10.1039/C1CC16590A

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