Issue 5, 2012
From the journal:

Chemical Communications

Photochromic hybrid materials of cucurbituril and polyoxometalates as photocatalysts under visible light†

Jian Lü,a   Jing-Xiang Lin,a   Xiu-Ling Zhaoab  and  Rong Cao*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, P. R. China
E-mail: rcao@fjirsm.ac.cn
Fax: +86 591 8371 4946
Tel: +86 591 8379 6710

b School of Chemistry, Xiangtan University, Hunan, Xiangtan 411105, P. R. China

Abstract

Two isostructural organic–inorganic hybrid solid materials based on cucurbituril derivatives and polyoxometalates, {[K2(H2O)2Na2(H2O)2Na2(H2O)6](P2W18O62)(Me10Q5)2}·∼7H2O (1) and {[Rb2(H2O)2Na2(H2O)Na2(H2O)4](P2W18O62)(Me10Q5)2}·∼8H2O (2), which exhibit reversible photochromic properties as well as excellent photocatalytic activities toward the degradation of methyl orange (MO) and rhodamine-B (RB) under visible light irradiation, are reported.

Graphical abstract: Photochromic hybrid materials of cucurbituril and polyoxometalates as photocatalysts under visible light

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Article information

DOI
https://doi.org/10.1039/C1CC16268C
Article type
Communication
Submitted
09 Oct 2011
Accepted
14 Nov 2011
First published
14 Nov 2011

Chem. Commun., 2012,48, 669-671

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Photochromic hybrid materials of cucurbituril and polyoxometalates as photocatalysts under visible light

J. Lü, J. Lin, X. Zhao and R. Cao, Chem. Commun., 2012, 48, 669 DOI: 10.1039/C1CC16268C

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