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Issue 1, 2012
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Pyridine encapsulated hyperbranched polymers as mimetic models of haeme containing proteins, that also provide interesting and unusual porphyrin-ligand geometries

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Abstract

This communication describes the use of non-covalent chemistry to construct recyclable porphyrin cored HBPs. The non-covalent design allows the polymeric backbone to be rescued and reused after porphyrin degradation. The steric environment within the polymeric encapsulated ligand notably affected the porphyrin coordination geometry.

Graphical abstract: Pyridine encapsulated hyperbranched polymers as mimetic models of haeme containing proteins, that also provide interesting and unusual porphyrin-ligand geometries

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Publication details

The article was received on 20 Jul 2011, accepted on 12 Oct 2011 and first published on 31 Oct 2011


Article type: Communication
DOI: 10.1039/C1CC14396D
Citation: Chem. Commun., 2012,48, 154-156
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    Pyridine encapsulated hyperbranched polymers as mimetic models of haeme containing proteins, that also provide interesting and unusual porphyrin-ligand geometries

    L. J. Twyman, A. Ellis and P. J. Gittins, Chem. Commun., 2012, 48, 154
    DOI: 10.1039/C1CC14396D

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