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Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
E-mail: Simon.Aldridge@chem.ox.ac.uk
; Fax: +44 (0)1865 272690
; Tel: +44 (0)1865 285201
Chem. Sci., 2011,2, 601-608
DOI:
10.1039/C0SC00508H
Received
04 Oct 2010,
Accepted
20 Jan 2011
First published online
08 Feb 2011
The Group 13 monohalides, EX, are valence isoelectronic with the key textbook diatomic molecules CO and N2; recent advances in synthetic chemistry leading to the isolation of transition metal complexes containing such fragments as ligands are appraised, together with studies of the electronic structure and reactivity of the coordinated molecules.
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