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Department of Chemistry and Institute for Catalysis in Energy Processes, Northwestern University, 2145 Sheridan Road, Evanston, USA
E-mail: j-hupp@northwestern.edu
; Fax: +1 847 491-7713 STN
; Tel: +1 847-467-3347 STN
Chem. Sci., 2011,2, 686-689
DOI:
10.1039/C0SC00339E
Received
18 Jun 2010,
Accepted
25 Oct 2010
First published online
04 Jan 2011
The synthesis of a porous organic polymer (POP) containing free-base porphyrin subunits has been accomplished by the condensation of a bis(phthalic acid)porphyrin with tetra(4-aminophenyl)methane. Metallation by post-synthesis modification affords microporous materials incorporating either Fe or Mn(porphyrins) that have been shown to be active catalysts for both olefinepoxidation and alkanehydroxylation.
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