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Issue 16, 2011
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A synergistic approach to polycyclics via a strategic utilization of Claisen rearrangement and olefin metathesis

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Abstract

Olefin metathesis promoted by a well-defined metal carbene complex has evolved into an efficient method for the construction of a broad range of carbocyclic and heterocyclic rings of varying size. The synthetic potential of the olefin metathesis has been further increased by combining various other C–C bond forming processes either in tandem or in sequence. Herein, application of Claisen rearrangement and olefin metathesis to prepare various intricate and/or biologically important targets has been described.

Graphical abstract: A synergistic approach to polycyclics via a strategic utilization of Claisen rearrangement and olefin metathesis

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Publication details

The article was received on 16 Mar 2011, accepted on 10 May 2011 and first published on 07 Jun 2011


Article type: Perspective
DOI: 10.1039/C1OB05413A
Citation: Org. Biomol. Chem., 2011,9, 5597-5624
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    A synergistic approach to polycyclics via a strategic utilization of Claisen rearrangement and olefin metathesis

    S. Kotha, N. G. Krishna, S. Halder and S. Misra, Org. Biomol. Chem., 2011, 9, 5597
    DOI: 10.1039/C1OB05413A

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