Issue 9, 2011

Rapid carbonylative coupling reactions using palladium(i) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers

Abstract

Palladium dimers with sterically hindered phosphines have been shown to be excellent pre-catalysts for the aminocarbonylation of aryl halides to yield amides and one of them has been successfully employed as a pre-catalyst for the synthesis of 11C-radiolabelled amides for PET imaging.

Graphical abstract: Rapid carbonylative coupling reactions using palladium(i) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers

Supplementary files

Article information

Article type
Paper
Submitted
14 Jan 2011
Accepted
24 Feb 2011
First published
25 Feb 2011

Org. Biomol. Chem., 2011,9, 3499-3503

Rapid carbonylative coupling reactions using palladium(I) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers

G. Buscemi, P. W. Miller, S. Kealey, A. D. Gee, N. J. Long, J. Passchier and R. Vilar, Org. Biomol. Chem., 2011, 9, 3499 DOI: 10.1039/C1OB05268C

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