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Issue 6, 2011
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Transannular dipolar cycloaddition as an approach towards the synthesis of the core ring system of the sarain alkaloids

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Abstract

Intramolecular transannular dipolar cycloaddition was investigated as a key step in a synthetic approach to the core of the sarain alkaloids; although the use of an azomethine ylide was unsuccessful with the chosen aldehyde substrate, cycloaddition with a nitrone did give the alternative regioisomeric bridged cycloadduct.

Graphical abstract: Transannular dipolar cycloaddition as an approach towards the synthesis of the core ring system of the sarain alkaloids

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Publication details

The article was received on 11 Nov 2010, accepted on 13 Dec 2010 and first published on 31 Jan 2011


Article type: Paper
DOI: 10.1039/C0OB01019G
Citation: Org. Biomol. Chem., 2011,9, 1901-1907
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    Transannular dipolar cycloaddition as an approach towards the synthesis of the core ring system of the sarain alkaloids

    A. I. Franklin, D. Bensa, H. Adams and I. Coldham, Org. Biomol. Chem., 2011, 9, 1901
    DOI: 10.1039/C0OB01019G

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