New synthetic route to N-tocopherol derivatives: synthesis of pyrrolopyridinol analogue of α-tocopherol from pyridoxine

Tae-gyu Nam; Jin-Mo Ku; Hyeung-geun Park; Ned A. Porter; Byeong-Seon Jeong

doi:10.1039/C0OB00991A

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Organic & Biomolecular Chemistry

Issue 6, 2011

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New synthetic route to N-tocopherol derivatives: synthesis of pyrrolopyridinol analogue of α-tocopherol from pyridoxine

Tae-gyu Nam , Jin-Mo Ku , Hyeung-geun Park , Ned A. Porter and Byeong-Seon Jeong

Org. Biomol. Chem., 2011, 9, 1749-1755

DOI: 10.1039/C0OB00991A
Received 08 Nov 2010, Accepted 02 Dec 2010
First published on the web 03 Dec 2010

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A new synthetic route to pyrrolopyridinol antioxidants from easily accessible pyridoxine was developed which includes phase-transfer catalytic alkylation and intramolecular Cu(I)-catalyzed amination as key steps.

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Tae-gyu Nam
Jin-Mo Ku
Hyeung-geun Park
Ned A. Porter
Byeong-Seon Jeong

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Organic & Biomolecular Chemistry

New synthetic route to N-tocopherol derivatives: synthesis of pyrrolopyridinol analogue of α-tocopherol from pyridoxine

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