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Issue 2, 2011
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2-Phenoxyethanol derived diselenide and related compounds; synthesis of a seven-membered seleninate ester

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Abstract

Syntheses of several diorganodiselenides and, in particular, a seven-membered cyclic seleninate ester derived from 2-phenoxyethanol are described. The seleninate ester was obtained from allyl (2-(2-hydroxyethoxy)phenyl) selenide through a series of oxidation and [2,3] sigmatropic rearrangement steps. The ester exhibits good GPx-like activity in the coupled reductase assay.

Graphical abstract: 2-Phenoxyethanol derived diselenide and related compounds; synthesis of a seven-membered seleninate ester

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Publication details

The article was received on 23 Apr 2010, accepted on 16 Sep 2010, published on 04 Nov 2010 and first published online on 04 Nov 2010


Article type: Paper
DOI: 10.1039/C0OB00038H
Citation: Org. Biomol. Chem., 2011,9, 581-587
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    2-Phenoxyethanol derived diselenide and related compounds; synthesis of a seven-membered seleninate ester

    S. K. Tripathi, S. Sharma, H. B. Singh and R. J. Butcher, Org. Biomol. Chem., 2011, 9, 581
    DOI: 10.1039/C0OB00038H

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